Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application

Paperback Engels 2021 9789811573507
Verwachte levertijd ongeveer 9 werkdagen

Samenvatting

This book provides detailed information on the base catalysis of group 5 (Nb, Ta) metal oxide clusters by elucidating how the structural factors such as constituent metals, counter cations, and local structures of base sites affect their catalysis. Uniquely, it reveals the effects of key structural factors at the molecular level by combining experimental and theoretical approaches. The findings presented here provide rational design principles for base catalysis and will foster the development of promising catalysts for solving current and future energy and environmental problems. 

Specificaties

ISBN13:9789811573507
Taal:Engels
Bindwijze:paperback
Uitgever:Springer Nature Singapore

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Inhoudsopgave

1. General Introduction.- 2. Application of Group 5 Polyoxometalate as an Efficient Base Catalyst: a Case Study of [Nb10O28]6–.- 3. Effect of Counter Cation on the Base Catalytic Activity of [Nb<sub>10</sub>O<sub>28</sub>]6<sup>–</sup>.- 4. Lewis Base Catalytic Properties of [Nb10O28]6− for CO2 Fixation to Epoxide: Kinetic and Theoretical Studies.- 5. Superior Base Catalysis of Group 5 Hexametalates over Group 6 Hexametalates.- 6. Concluding Remarks.

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        Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application